Water Pollution
Water pollution is the contamination of water bodies ( lakes,
rivers, oceans and groundwater). Water pollution affects plants and
organisms living in these bodies of water and in almost all cases the
effect is damaging not only to individual species and populations, but
also to the natural communities.
Water pollution occurs when pollutants are discharged directly or
indirectly into water bodies without adequate treatment to remove
harmful compounds. Point source pollution refers to contaminants that
enter a waterway through a discrete conveyance, such as a pipe or ditch.
Examples of sources in this category include discharges from a sewage
treatment plant, a factory, or a city storm drain.
Non-point
source pollution: Non-point source (NPS) pollution refers to diffuse
contamination that does not originate from a single discrete source. NPS
pollution is often the cumulative effect of small amounts of
contaminants gathered from a large area. The leaching out of nitrogen
compounds from agricultural land which has been fertilized is a typical
example. Nutrient runoff in storm water from “sheet flow” over an
agricultural field or a forest are also cited as examples of NPS
pollution.
Contaminated storm water washed off of parking lots,
roads and highways, called urban runoff, is sometimes included under the
category of NPS pollution. However, this runoff is typically channelled
into storm drain systems and discharged through pipes to local surface
waters, and is a point source. However where such water is not channeled and drains directly to ground it is a non-point source.
Types of Water Pollution:
There are two types of water pollution: Ground water pollution & Surface water pollution
i. Groundwater Pollution:
Considerable
amount of Earth’s water is found in soil or under rock structures
called aquifers. People use aquifers to obtain drinking water and build
wells to access it. In case this water becomes polluted, it is called
groundwater pollution. This is caused by pesticide contamination from
the soil and this can infect the drinking water and lead to huge
problems.
Groundwater refers to water collected under the Earth’s surface. The
sources of groundwater are rain, snow, hail, sleet, etc. Water that
falls on the Earth’s surface continues to travel downwards due to
gravity, until a zone comes where it is saturated with water.
At
this depth, the spaces between the soil and rock particles are filled up
with water. This particular zone is known as the saturated zone. The
topmost portion of the saturated zone is referred to as water table. The
level of water table changes depending upon the season, it is highest
in spring and lowest in summer.
Groundwater is connected to
surface water such as rivers, streams and lakes. In fact, there is
continuous exchange of water between surface water and groundwater.
Groundwater pollution is a change in the properties of groundwater due
to contamination by microbes, chemicals, hazardous substances and other
foreign particles. It is a major type of water pollution. The sources of
groundwater pollution are either natural (mineral deposits in rocks) or
man-made.
Natural sources are less harmful compared to hazardous chemicals
generated by human activities. Any chemical present on the surface can
travel underground and cause groundwater pollution. The seepage of the
chemical depends on the chemical type, soil porosity and hydrology.
One
of the major sources of groundwater pollution is industries.
Manufacturing and other chemical industries require water for processing
and cleaning purposes. This used water is recycled back to water
sources without proper treatment, which in turn, results in groundwater
pollution.
It is also to be noted that solid industrial wastes
that are dumped in certain areas also contribute to groundwater
pollution. When rainwater seeps downwards, it dissolves some of these
harmful substances and contaminates groundwater.
Another source of
groundwater pollution is agriculture; the fertilizers, pesticide and
other chemicals used in growing plants contaminate groundwater.
Residential areas also generate pollutants (microorganisms and organic
compounds) for groundwater contamination.
Groundwater pollutant can be divided into point source and non-point
source based on the nature of disposal. The former refers to
contaminants originating from a particular source such as sewage pipe or
tank; whereas non-point source is spread over large areas (for example,
pesticides and fertilizers).
It is very difficult and costly to treat contaminated groundwater.
Hence, it is better to minimize the risk of groundwater pollution.
Public awareness programs about the importance of groundwater and ways
to minimize its contamination should be implemented.
ii. Surface Water Pollution:
These
are the natural water resources of the Earth. These are found on the
exterior of the Earth’s crust, oceans, rivers and lakes.
Water is
an essential commodity for survival. We need water for drinking,
cooking, bathing, washing, irrigation, and for industrial operations.
Most of the water for such uses comes from rivers, lakes or groundwater
sources. Water has the property to dissolve many substances in it,
therefore, it can easily get polluted.
Pollution of water can be
caused by “point sources” or “non- point sources”. Point sources are
specific sites near water which directly discharge effluents into them.
Major point sources of water pollution are industries, power plants,
underground coal mines, offshore oil wells etc.
The discharge from
non-point sources is not at any particular site, rather, these sources
are scattered, which individually or collectively pollute water. Surface
run-off from agricultural fields, overflowing small drains, rain water
sweeping roads and fields, atmospheric deposition etc., are the
non-point sources of water pollution.
Sources of Surface Water Pollution:
1. Sewage:
Emptying the drains and sewers in fresh water bodies causes water pollution. The problem is severe in cities.
2. Industrial Effluents:
Industrial
wastes containing toxic chemicals, acids, alkalies, metallic salts, phenol's, cyanides, ammonia, radioactive substances, etc., are sources of
water pollution.They also cause thermal (heat) pollution of water.
3. Synthetic Detergents:
Synthetic detergents used in washing and cleaning produce foam and pollute water.
4. Agrochemicals:
Agrochemicals
like fertilizers (containing nitrates and phosphates) and pesticides
(insecticides, fungicides, herbicides etc.) washed by rain-water and
surface runoff pollute water.
5. Oil:
Oil spillage into sea-water during drilling and shipment pollute it.
6. Waste heat:
Waste
heat from industrial discharges increases the temperature of water
bodies and affects distribution and survival of sensitive species.
Sources and Types of Water Pollutants:
Pathogens:
Coli-form bacteria are a commonly used bacterial indicator of water pollution,
although not an actual cause of disease. Other microorganisms sometimes
found in surface waters which have caused human health problems include:
i. Burkholderia pseudomallei.
ii. Cryptosporidium parvum.
iii. Giardia lamblia.
iv. Salmonella.
v. Novovirus and other viruses.
vi. Parasitic worms (helminths).
High
levels of pathogens may result from inadequately treated sewage
discharges. This can be caused by a sewage plant designed with less than
secondary treatment (more typical in less- developed countries. In
developed countries, older cities with aging infrastructure may have
leaky sewage collection systems (pipes, pumps, valves), which can cause
sanitary sewer overflows. Some cities also have combined sewers, which
may discharge untreated sewage during rain storms. Pathogen discharges
may also be caused by poorly managed livestock operations.
Chemical and other contaminants: Contaminants may include organic and inorganic substances.
Organic water pollutants include:
i. Detergents.
ii. Disinfection by-products found in chemically disinfected drinking water, such as chloroform.
iii. Food processing waste, which can include oxygen-demanding substances, fats and grease.
iv. Insecticides and herbicides, a huge range of organohalides and other chemical compounds.
v.
Petroleum hydrocarbons, including fuels (gasoline, diesel fuel, jet
fuels, and fuel oil) and lubricants (motor oil), and fuel combustion
by-products, from storm water runoff.
vi. Tree and bush debris from logging operations.
vii. Volatile organic compounds (VOCs), such as industrial solvents.
viii. Various chemical compounds found in personal hygiene and cosmetic products.
Inorganic water pollutants are:
i. Pre-production industrial raw resin pellets.
ii. Heavy metals including acid mine drainage, chemical waste as industrial by-products.
iii. Acidity due to industrial discharges like sulphur dioxide.
iv. Silt in surface runoff due to logging, slash and burn practices, construction sites or land clearing sites.
v. Fertilizers in runoff from agriculture including nitrates and phosphates.
Other agents:
i.
The combustion of coal leads to the release of mercury in the
atmosphere. This enters the rivers, lakes and groundwater. This is very
hazardous for pregnant women and infants.
ii. Cattle and pig rearing causes a significant amount of nutrient-filled waste.
iii.
Fertilizers having a large quantity of nitrogen and phosphorus cause a
high biological oxygen demand in the water. The high amount of BOD is
responsible for oxygen depletion in water bodies.
iv. Human settlement along the banks of rivers causes human, animal and industrial waste to be discharged into it.
Effect of Water Pollution:
i. Disorders:
Some pollutants like sodium can cause cardiovascular diseases, while mercury and lead cause nervous disorders.
ii. Toxic Substances:
DDT
is toxic material which can cause chromosomal changes. Some of these
substances like pesticides, methyl mercury etc., move into the bodies of
organisms from the medium in which these organisms live. These
substances tend to accumulate in the organism’s body from the medium
food. This process is called bioaccumulation or bio concentration. The
concentration of these toxic substances builds up at successive levels
of food chain. This process is called bio magnifications.
iii. Water Pollution:
Fluoride
pollution causes defects in teeth and bones, a disease called fluorosis
while arsenic can cause significant damage to the liver and the nervous
system. In addition to all these, organic compounds present in the
polluted water facilitate the growth of algae and other weeds, which in
turn use more oxygen dissolved in the water. This reduces the amount of
oxygen dissolved in the water and the consequent shortage of oxygen for
other aquatic life.
iv. Asbestos:
This pollutant is a
serious health hazard and carcinogenic. Asbestos fibers can be inhaled
and cause illnesses such as asbestosis, mesothelioma, lung cancer,
intestinal cancer and liver cancer.
v. Mercury:
This
is a metallic element and can cause health and environmental problems.
It is a non-biodegradable substance so is hard to clean up once the
environment is contaminated. Mercury is also harmful to animal health as
it can cause illness through mercury poisoning.
vi. Phosphates:
The
increased use of fertilizers means that phosphates are more often being
washed from the soil and into rivers and lakes. This can cause
eutrophication, which can be very problematic to marine environments.
vii. Oils:
Oil
does not dissolve in water; instead it forms a thick layer on the water
surface. This can stop marine plants receiving enough light for
photosynthesis. It is also harmful for fish and marine birds.
viii. Petrochemicals:
This is formed from gas or petrol and can be toxic to marine life.
ix.
Organic matter which reaches water bodies is decomposed by
micro-organisms present in water. For this degradation, oxygen dissolved
in water is consumed. Dissolved oxygen (DO) is the amount of oxygen
dissolved in a given quantity of water at a particular temperature and
atmospheric pressure.
Amount of dissolved oxygen depends on
aeration, photosynthetic activity in water, respiration of animals and
plants and ambient temperature.The saturation value of DO varies from
8-15 mg/L. For active fish species (trout and Salmon) 5-8 mg/L of DO is
required whereas less desirable species like carp can survive at 3.0
mg/L of DO.Lower DO may be harmful to animals especially fish
population. Oxygen depletion (deoxygenating) helps in release of
phosphates from bottom sediments and causes eutrophication.
x. Addition
of compounds containing nitrogen and phosphorus helps in the growth of
algae and other plants which when die and decay consume oxygen of water.
Under anaerobic conditions foul smelling gases are produced. Excess
growth or decomposition of plant material will change the concentration
of CO
2 which will further change pH of water. Changes in pH,
oxygen and temperature will change many physicochemical characteristics
of water.
xi. Lead in water may be released from water
pipes as lead is used in plumbing. Lead poisoning affects kidneys
reproductive system, liver, brain and central nervous system. It also
causes anaemia and mental retardation in children.
xii.
Nitrate ions present in the water are harmful to human health. From
nitrogen fertilizers, nitrate ions seep into water bodies from where
these may bioaccumulate in the bodies of the consumers. In the stomach
nitrate is reduced to nitrite and is responsible for blue baby syndrome
and stomach cancer.
Control of Water Pollution:
The following points may help in reducing water pollution from non-point sources.
(i)
Judicious use of agrochemicals like pesticides and fertilizers which
will reduce their surface run-off and leaching. Use of these on sloped
lands should be avoided.
(ii) Use of nitrogen fixing plants to supplement the use of fertilizers.
(iii) Adopting integrated pest management to reduce greater reliance on pesticides.
(iv)
Prevent run-off of manure. Divert such run-off to basin for settlement.
The nutrient rich water can be used as fertilizer in the fields.
(v) Separate drainage of sewage and rain water should be provided to prevent overflow of sewage with rain water.
(vi) Planting trees would reduce pollution by sediments and will also prevent soil erosion.
For
controlling water pollution from point sources, treatment of waste
waters is essential before being discharged. Parameters which are
considered for reduction in such water are: Total solids, biological
oxygen demand (BOD), chemical oxygen demand (COD), nitrates and
phosphates, oil and grease, toxic metals etc. Waste waters should be
properly treated by primary and secondary treatments to reduce the BOD,
COD levels up to the permissible levels for discharge.
Sewage
treatment, or domestic wastewater treatment, is the process of removing
contaminants from wastewater and household sewage, both runoff
(effluents) and domestic. It includes physical, chemical, and biological
processes to remove physical, chemical and biological contaminants. Its
objective is to produce an environmentally-safe fluid waste stream (or
treated effluent) and a solid waste (or treated sludge) suitable for
disposal or reuse (usually as farm fertilizer).
Sewage is created
by residential, institutional, and commercial and industrial
establishments and includes household waste liquid from toilets, baths,
showers, kitchens, sinks and so forth that is disposed of via sewers. In
many areas, sewage also includes liquid waste from industry.
Sewage
can be treated close to where it is created (in septic tanks,
bio-fitter’s or aerobic treatment systems), or collected and transported
via a network of pipes and pump stations to a municipal treatment
plant.
Sewage collection and treatment is typically subject to
local, state and federal regulations and standards. Industrial sources
of wastewater often require specialized treatment processes (see
Industrial wastewater treatment).
Conventional sewage treatment
may involve three stages, called primary, secondary and tertiary
treatment. Primary treatment consists of temporarily holding the sewage
in a quiescent basin where heavy solids can settle to the bottom while
oil, grease and lighter solids float to the surface. The settled and
floating materials are removed and the remaining liquid may be
discharged or subjected to secondary treatment.
Secondary
treatment removes dissolved and suspended biological matter. Secondary
treatment is typically performed by indigenous, water-borne
micro-organisms in a managed habitat. Secondary treatment may require a
separation process to remove the microorganisms from the treated water
prior to discharge or tertiary treatment.
Tertiary treatment is
sometimes defined as anything more than primary and secondary treatment.
Treated water is sometimes disinfected chemically or physically (for
example, by lagoons and microfiltration) prior to discharge into a
stream, river, bay, lagoon or wetland, or it can be used for the
irrigation of a golf course, green way or park. If it is sufficiently
clean, it can also be used for groundwater recharge or agricultural
purposes.
i. Pre-treatment removes materials that can be easily
collected from the raw wastewater before they damage or clog the pumps
and skimmers of primary treatment clarifiers (trash, tree limbs, leaves,
etc.).
ii. Screening:
The influent sewage water is
screened to remove all large objects carried in the sewage stream. This
is most commonly done with an automated mechanically raked bar screen in
modern plants serving large populations, whilst in smaller or less
modern plants a manually cleaned screen may be used.
The raking
action of a mechanical bar screen is typically paced according to the
accumulation on the bar screens and/or flow rate. The solids are
collected and later disposed in a landfill or incinerated. Bar screens
or mesh screens of varying sizes may be used to optimize solids removal.
If gross solids are not removed they become entrained in pipes and
moving parts.
iii. Grit removal:
Pre-treatment may
include a sand or grit channel or chamber where the velocity of the
incoming wastewater is adjusted to allow the settlement of sand, grit,
stones, and broken glass. These particles are removed because they may
damage pumps and other equipment. For small sanitary sewer systems, the
grit chambers may not be necessary, but grit removal is desirable at
larger plants.
iv. Fat and grease removal:
Fat and
grease is removed by passing the sewage through a small tank where
skimmers collect the fat floating on the surface. Air blowers in the
base of the tank may also be used to help recover the fat as froth. In
most plants however, fat and grease removal takes place in the primary
settlement tank using mechanical surface skimmers.
v. Primary treatment:
In
the primary sedimentation stage, sewage flows through large tanks,
commonly called “primary clarifiers” or “primary sedimentation tanks.”
The tanks are used to settle sludge while grease and oils rise to the
surface and are skimmed off.
Primary settling tanks are usually
equipped with mechanically driven scrapers that continually drive the
collected sludge towards a hopper in the base of the tank where it is
pumped to sludge treatment facilities. Grease and oil from the floating
material can sometimes be recovered for saponification.
The
dimensions of the tank should be designed to effect removal of a high
percentage of the floatables and sludge. A typical sedimentation tank
may remove from 60 to 65 per cent of suspended solids, and from 30 to 35
per cent of biochemical oxygen demand (BOD) from the sewage.
vi. Secondary treatment:
Secondary
treatment is designed to substantially degrade the biological content
of the sewage which is derived from human waste, food waste, soaps and
detergent. The majority of municipal plants treat the settled sewage
liquor using aerobic biological processes. To be effective, the biota
requires both oxygen and food to live.
The bacteria and protozoa
consume biodegradable soluble organic contaminants (e.g. sugars, fats,
organic short-chain carbon molecules, etc.) and bind much of the less
soluble fractions into floe. Secondary treatment systems are classified
as fixed-film or suspended-growth systems.
Fixed-film or attached
growth systems include trickling filters and rotating biological
contactors, where the biomass grows on media and the sewage passes over
its surface. Suspended-growth systems include activated sludge, where
the biomass is mixed with the sewage and can be operated in a smaller
space than fixed-film systems that treat the same amount of water.
However,
fixed-film systems are more able to cope with drastic changes in the
amount of biological material and can provide higher removal rates for
organic material and suspended solids than suspended growth systems.
vii. Rotating biological contactors:
Rotating biological
contactors (RBCs) are mechanical secondary treatment systems, which are
robust and capable of withstanding surges in organic load. RBCs were
first installed in Germany in 1960 and have since been developed and
refined into a reliable operating unit.
The rotating disks support
the growth of bacteria and micro-organisms present in the sewage, which
break down and stabilize organic pollutants. To be successful,
micro-organisms need both oxygen to live and food to grow. Oxygen is
obtained from the atmosphere as the disks rotate. As the micro-organisms
grow, they build up on the media until they are sloughed off due to
shear forces provided by the rotating discs in the sewage.
Effluent
from the RBC is then passed through final clarifiers where the
micro-organisms in suspension settle as sludge. The sludge is withdrawn
from the clarifies for further treatment. A functionally similar
biological filtering system has become popular as part of home aquarium
filtration and purification.
The aquarium water is drawn up out of
the tank and then cascaded over a freely spinning corrugate fiber-mesh
wheel before passing through a media filter and back into the aquarium.
The spinning mesh wheel develops a bio film coating of microorganisms
that feed on the suspended wastes in the aquarium water and are also
exposed to the atmosphere as the wheel rotates. This is especially good
at removing waste urea and ammonia urinated into the aquarium water by
the fish and other animals.
viii. Biological aerated filters:
The
removal of nitrogen is effected through the biological oxidation of
nitrogen from ammonia (nitrification) to nitrate, followed by De-nitrification, the reduction of nitrate to nitrogen gas. Nitrogen gas
is released to the atmosphere and thus removed from the water.
Nitrification itself is a two-step aerobic process, each step
facilitated by a different type of bacteria.
The oxidation of ammonia (NH
3) to nitrite (NO
3)
is most often facilitated by Nitrosomonas spp. (nitroso referring to
the formation of a nitroso functional group). Nitrite oxidation to
nitrate (NO
3), though traditionally believed to be
facilitated by Nitrobacter spp. (nitro referring the formation of a
nitro functional group), is now known to be facilitated in the
environment almost exclusively by Nitrospira spp.De-nitrification
requires anoxic conditions to encourage the appropriate biological
communities to form. It is facilitated by a wide diversity of bacteria.
ix. Secondary sedimentation:
The
final step in the secondary treatment stage is to settle out the
biological floe or filter material through a secondary clarifier and to
produce sewage water containing low levels of organic material and
suspended matter.
x. Tertiary treatment:
The purpose
of tertiary treatment is to provide a final treatment stage to raise the
effluent quality before it is discharged to the receiving environment
(sea, river, lake, ground, etc.). More than one tertiary treatment
process may be used at any treatment plant. If disinfection is
practiced, it is always the final process. It is also called “effluent
polishing.”
xi. Sand filtration removes much of the
residual suspended matter. Filtration over activated carbon, also called
carbon adsorption, removes residual toxins.
xii. Lagooning
provides settlement and further biological improvement through storage
in large man-made ponds or lagoons. These lagoons are highly aerobic and
colonization by native macrophytes, especially reeds, is often
encouraged. Small filter feeding invertebrates such as Daphnia and
species of Rotifera greatly assist in treatment by removing fine
particulates.
Sludge treatment & disposal:
i. Anaerobic digestion:
Anaerobic
digestion is a bacterial process that is carried out in the absence of
oxygen. The process can either be thermophilic digestion, in which
sludge is fermented in tanks at a temperature of 55°C, or mesophilic, at
a temperature of around 36°C.
Though allowing shorter retention
time (and thus smaller tanks), thermophilic digestion is more expensive
in terms of energy consumption for heating the sludge. Anaerobic
digestion is the most common (mesophilic) treatment of domestic sewage
in septic tanks, which normally retain the sewage from one day to two
days, reducing the BOD by about 35 to 40 percent.
This reduction
can be increased with a combination of anaerobic and aerobic treatment
by installing Aerobic Treatment Units (ATUs) in the septic tank. One
major feature of anaerobic digestion is the production of biogas (with
the most useful component being methane), which can be used in
generators for electricity production and/or in boilers for heating
purposes.
ii. Aerobic digestion:
Aerobic digestion is
a bacterial process occurring in the presence of oxygen. Under aerobic
conditions, bacteria rapidly consume organic matter and convert it into
carbon dioxide. The operating costs used to be characteristically much
greater for aerobic digestion because of the energy used by the blowers,
pumps and motors needed to add oxygen to the process. Aerobic digestion
can also be achieved by using diffuser systems or jet aerators to
oxidize the sludge.
iii. Composting:
Composting is
also an aerobic process that involves mixing the sludge with sources of
carbon such as sawdust, straw or wood chips. In the presence of oxygen,
bacteria digest both the wastewater solids and the added carbon source
and, in doing so, produce a large amount of heat.
iv. Incineration:
Incineration
of sludge is less common because of air emissions concerns and the
supplemental fuel (typically natural gases or fuel oil) required to burn
the low calorific value sludge and vaporize residual water.
Stepped
multiple hearth incinerators with high residence time and fluidized bed
incinerators are the most common systems used to combust wastewater
sludge. Co-firing in municipal waste-to-energy plants is occasionally
done, this option being less expensive assuming the facilities already
exist for solid waste and there is no need for auxiliary fuel.
v. Sludge disposal:
When
a liquid sludge is produced, further treatment may be required to make
it suitable for final disposal. Typically, sludge’s are thickened
(dewatered) to reduce the volumes transported off-site for disposal.
There
is no process which completely eliminates the need to dispose of
bio-solids. There is, however, an additional step some cities are taking
to superheat sludge and convert it into small pelletized granules that
are high in nitrogen and other organic materials.